While it may seem logical that to lighten a color you add white to it and that to darken it you add black, this is an oversimplification. White reduces brightness so although it makes a color lighter, it removes its vibrancy. Black doesn't so much add darkness as create murkiness.

Why can't I add white to lighten a color?
Adding white to a color produces a tint of that color, makes a transparent color (such as ultramarine) opaque, and cools the color. This is most noticeable with red, which changes from a warm red into a cool pink. You can add white to lighten a color, but because this removes the vibrancy of a color you'll end up with a washed-out picture if you use white to lighten all you colors. Rather develop your color mixing skills to produce hues of varying intensity. For example, to lighten a red, add some yellow instead than white.


But there isn't a white in watercolor...
Watercolor paints are transparent, so to lighten you simply add more water to paint to let the white of the paper shine through.

Why can't I add black to darken a color?
Black tends to dirty colors rather than darken them. Of the most common blacks, Mars black is the blackest and is very opaque, ivory black has a brown undertone, and lamp black a blue undertone. Think about how much is truly black in nature.

Aren't shadows black?
No, shadows are not simply black nor a darker version of the color of the object. They contain the complementary color of the object. Take, for example, the shadow on a yellow object. If you mix black and yellow, you get an unattractive olive green. Instead of using this for the shadow, use a deep purple. Purple being the complementary color of yellow, both will look more vibrant.

I can't figure out what colors are in the shadows...
Simplify what you're looking at by placing your hand or a piece of white paper next to the bit you're having trouble with, then look again.

Haven't painters always used black?
The Impressionists didn't use black at all. Take a look at Monet's paintings of Rouen Cathedral in full sunlight, in dull weather, and in blue and gold to see what a genius can do with shadows (he did 20 paintings of the cathedral at different times of the day).


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